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Characterization of the Nucleophilic Allylindium Species Generated from Allyl Bromide and Indium(0) in Aqueous Media (Eur. J. Org. Chem. 28/2010)
Author(s) -
Yasuda Makoto,
Haga Masahiko,
Nagaoka Yasunori,
Baba Akio
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201090076
Subject(s) - chemistry , allyl bromide , bromide , indium , nucleophile , aqueous medium , medicinal chemistry , aqueous solution , organic chemistry , catalysis
The cover picture shows the species generated in the reductive system of allyl bromide with indium(0) in water. They include monoallylindium(III) dibromide, diallylindium(III) bromide, and allyl(μ‐oxido)indium(III). These compounds were characterized on the basis of X‐ray analysis. The allylindium compounds showed nucleophilicity towards carbonyl compounds with different reactivities. Details are discussed in the Short Communication by M. Yasuda, A. Baba et al. on p. 5359 ff.