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Direct Synthesis of Organic Azides from Primary Amines with 2‐Azido‐1,3‐dimethylimidazolinium Hexafluorophosphate
Author(s) -
Kitamura Mitsuru,
Yano Masakazu,
Tashiro Norifumi,
Miyagawa Satoshi,
Sando Mitsuyoshi,
Okauchi Tatsuo
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001509
Subject(s) - chemistry , hexafluorophosphate , primary (astronomy) , organic chemistry , combinatorial chemistry , catalysis , ionic liquid , physics , astronomy
Organic azides were prepared from primary amines in high yields by metal‐free diazo transfer with 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate, which is a stable, crystalline solid that is easy to handle.
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