Construction and Properties of a Phototriggered Cd 2+  Release System | Zendy

Zhang Xu | Zendy; Chen Yi | Zendy

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Construction and Properties of a Phototriggered Cd 2+ Release System

Author(s) -

Zhang Xu,

Chen Yi

Publication year - 2011

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201001500

Subject(s) - chemistry , benzothiazole , fluorescence , photochemistry , ligand (biochemistry) , derivative (finance) , organic chemistry , receptor , biochemistry , physics , quantum mechanics , financial economics , economics

A phototriggered Cd 2+ release complex has been prepared by using benzothiazoline as a ligand. With visible‐light ( λ ≥ 400 nm) irradiation, bound Cd 2+ can be released from the complex, and the ligand is converted into a benzothiazole derivative. Accompanying the process of photoconversion, turn‐on fluorescence is observed. The fluorescence intensity increases with photoconversion until Cd 2+ is completely released, which provides a convenient method to monitor the phototriggered Cd 2+ release process.

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