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Heterogeneous Catalytic Reactions “On Water” by Using Stable Polymeric Alkynylcopper(I) Pre‐Catalysts: Alkyne/Azide Cycloaddition Reactions
Author(s) -
Buckley Benjamin R.,
Dann Sandra E.,
Heaney Harry,
Stubbs Emma C.
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001326
Subject(s) - cycloaddition , chemistry , alkyne , catalysis , azide , copper , click chemistry , polymer chemistry , combinatorial chemistry , organic chemistry
Dinuclear alkynylcopper(I) complexes have been found to be the active pre‐catalysts in copper‐catalysed cycloaddition of azides and terminal alkynes (CuAAC). These copper(I) ladderane polymers are used in “on water” CuAAC reactions, with loadings as low as 1 mol‐%.