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Synthesis of Aminocyclitols and Trihydroxylated Indolizidinone from a D ‐Mannitol‐Derived Common Building Block
Author(s) -
Gupta Preeti,
Pal A. P. John,
Reddy Y. Suman,
Vankar Yashwant D.
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001171
Subject(s) - chemistry , dihydroxylation , mannitol , d mannitol , metathesis , stereochemistry , hydroxylation , biochemistry , enantioselective synthesis , organic chemistry , enzyme , catalysis , polymer , polymerization
The synthesis of 4‐amino‐4‐deoxy‐ muco ‐quercitol ( 22 ), 4‐amino‐4‐deoxy‐(–)‐ vibo ‐quercitol ( 27 ) and also a trihydroxylated indolizidinone 38 from D ‐mannitol is described using ring‐closing metathesis and diastereoselective dihydroxylation as the key steps.