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P ‐Phenyl‐2,2,6,6‐tetramethylphosphorinan‐4‐ol: An Air‐Stable P,O‐Type Ligand for Palladium‐Mediated Cross‐Coupling Reactions
Author(s) -
Ullah Ehsan,
McNulty James,
Larichev Vladimir,
Robertson Al J.
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001099
Subject(s) - chemistry , palladium , ligand (biochemistry) , coupling (piping) , coupling reaction , medicinal chemistry , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , receptor , mechanical engineering , biochemistry , engineering
Abstract A two‐step entry to a chemically robust, hindered P,O‐type phosphorinane‐based ligand and its application toward Pd‐mediated cross‐coupling reactions of unactivated aryl chlorides is presented.