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Solvent Effects on the Steric Course of the [2,3]‐Wittig Rearrangement of ( S , E )‐[3‐(Allyloxy)prop‐1‐ene‐1,3‐diyl]dibenzene and Derivatives
Author(s) -
Ikemoto Hidaka,
Sasaki Michiko,
Takeda Kei
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201001061
Subject(s) - chemistry , steric effects , carbanion , wittig reaction , intramolecular force , chirality (physics) , solvent effects , solvent , claisen rearrangement , medicinal chemistry , stereochemistry , organic chemistry , chiral symmetry breaking , nambu–jona lasinio model , quark , physics , quantum mechanics
The effect of solvents and additives on the steric course of [2,3]‐Wittig rearrangement of the chiral 1,3‐diphenyl‐1‐propenyloxy‐2‐propen‐1‐yl carbanion and its derivatives wasexamined on the basis of chirality transfer in intramolecular trapping.