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A Simple and Effective Method for α‐Hydroxylation of β‐Dicarbonyl Compounds Using Oxone as an Oxidant without a Catalyst
Author(s) -
Yu Jun,
Cui Jian,
Zhang Chi
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000940
Subject(s) - chemistry , reagent , hydroxylation , catalysis , homogeneous , solvent , organic chemistry , homogeneous catalysis , combinatorial chemistry , green chemistry , reaction mechanism , physics , thermodynamics , enzyme
Oxone has been found to be a highly efficient reagent for the introduction of a hydroxy group at the α position of a variety of β‐dicarbonyl compounds in the homogeneous solvent mixture of water and 1,4‐dioxane at 60 °C.