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One‐Pot Stereoselective Double Intramolecular Oxymercuration: Synthesis of Four Isomers of an Unsymmetrical Bis‐Tetrahydrofuran Ring System
Author(s) -
Mohapatra Debendra K.,
Naidu P. Ramesh,
Reddy D. Srinivas,
Nayak Sabita,
Mohapatra Seetaram
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000861
Subject(s) - tetrahydrofuran , chemistry , stereoselectivity , intramolecular force , ring (chemistry) , stereochemistry , organic chemistry , catalysis , solvent
Stereoselective one‐pot double intramolecular oxymercuration has been demonstrated to be the key reaction in the efficient preparation of the mono‐hydroxylated bis‐tetrahydrofuran ring system present in asimitrin and salzmanolin, two naturally occurring biologically active nonclassical acetogenins.