Sulfonato–Cu(salen) Complex Catalyzed  N ‐Arylation of Aliphatic Amines with Aryl Halides in Water | Zendy

Wu Zhiqing | Zendy; Zhou Li | Zendy; Jiang Zhaoqiong | Zendy; Wu Di | Zendy; Li Zhengkai | Zendy; Zhou Xiangge | Zendy

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Sulfonato–Cu(salen) Complex Catalyzed N ‐Arylation of Aliphatic Amines with Aryl Halides in Water

Author(s) -

Wu Zhiqing,

Zhou Li,

Jiang Zhaoqiong,

Wu Di,

Li Zhengkai,

Zhou Xiangge

Publication year - 2010

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201000840

Subject(s) - chemistry , aryl , catalysis , amination , halide , organic chemistry , condensation , amine gas treating , medicinal chemistry , polymer chemistry , physics , thermodynamics , alkyl

A water‐soluble sulfonato‐Cu(salen) complex catalyzed procedure for the N ‐arylation of simple aliphatic amines, amino alcohols and amino acids in pure water have been developed. A variety of substituted aryl iodides, bromides and electron‐deficient chlorides were found to be applicable, and 1,2‐disubstituted benzimidazoles could be prepared easily by a cascade amination/condensation process in this catalytic system.

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