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Hydrogenation and Dehydrogenation of Pentaphenylcyclopentadienes and Pentaphenylcyclopentenes
Author(s) -
Kanthak Matthias,
Muth Enrico,
Dyker Gerald
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000821
Subject(s) - dehydrogenation , chemistry , catalysis , photochemistry , organic chemistry
Pentaaryl‐substituted cyclopentadienes and cyclopentenes have been employed in catalytic hydrogenation and photochemical cyclodehydrogenation reactions, targeting strained bowl‐shaped structures. Both types of reactions generally stop at the monohydrogenation and monocyclization stage, respectively.