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C(sp 3 )–C(sp 3 ) Bond Breaking in Methylenecyclopropanes Involving a Au I /Au III Catalytic Cycle
Author(s) -
Zhang DiHan,
Dai LunZhi,
Shi Min
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000765
Subject(s) - chemistry , acetic acid , catalysis , medicinal chemistry , stereochemistry , organic chemistry
Gold(I) can catalyze the diacetoxylation of methylenecyclopropanes to produce the corresponding diacetoxylated products in moderate to good yields in acetic acid in the presence of iodosobenzene diacetate via C–C bond breaking under mild condition.