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In III ‐Catalysed Tandem C–C and C–O Bond Formation between Phenols and Allylic Acetates
Author(s) -
Vece Vito,
Ricci Jérémy,
PoulainMartini Sophie,
Nava Paola,
Carissan Yannick,
Humbel Stéphane,
Duñach Elisabet
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000738
Subject(s) - chemistry , allylic rearrangement , trifluoromethanesulfonate , intramolecular force , tandem , catalysis , ring (chemistry) , medicinal chemistry , phenols , stereochemistry , organic chemistry , materials science , composite material
Indium triflate catalysed tandem allylation–intramolecular hydroalkoxylation was efficiently carried out by using 1 mol‐% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman‐type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented.