Premium
Chiral Triphenylprolinol Ligands for the Efficient Catalytic Asymmetric Arylation of Aldehydes
Author(s) -
Moro Angélica Venturini,
Tiekink Edward R. T.,
ZukermanSchpector Julio,
Lüdtke Diogo S.,
Correia Carlos Roque D.
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201000336
Subject(s) - chemistry , enantioselective synthesis , catalysis , combinatorial chemistry , organic chemistry , heck reaction , aldehyde , palladium
The synthesis of new chiral amino alcohols by Heck arylation of an enecarbamate is described. These compounds were used as chiral ligands for the catalytic asymmetric arylation of aldehydes and can be easily recovered. Chiral, nonracemic diarylmethanols were obtained in high yields and enantioselectivities.