Noyori's Ts‐DPEN Ligand: Simple yet Effective Catalyst for the Highly Enantioselective Michael Addition of Acetone to Nitroalkenes | Zendy

Peng Lin | Zendy; Xu XiaoYing | Zendy; Wang LiangLiang | Zendy; Huang Jun | Zendy; Bai JianFei | Zendy; Huang QingChun | Zendy; Wang LiXin | Zendy

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Noyori's Ts‐DPEN Ligand: Simple yet Effective Catalyst for the Highly Enantioselective Michael Addition of Acetone to Nitroalkenes

Author(s) -

Peng Lin,

Xu XiaoYing,

Wang LiangLiang,

Huang Jun,

Bai JianFei,

Huang QingChun,

Wang LiXin

Publication year - 2010

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200901509

Subject(s) - enantioselective synthesis , chemistry , bifunctional , acetone , michael reaction , ligand (biochemistry) , terephthalic acid , catalysis , organic chemistry , amine gas treating , organocatalysis , combinatorial chemistry , polyester , biochemistry , receptor

Highly enantioselective Michael addition of acetone to a variety of nitroalkenes promoted by simple chiral primary amine bifunctional catalysts (e.g., Noyori's Ts‐DPEN ligand) together with terephthalic acid in excellent yields (84–99 %) and enantioselectivities (93–98 % ee ) is reported.

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