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Simple, One‐Pot, and Facile Synthesis of Angularly Fused [6‐7‐5], [6‐7‐6], [6‐7‐7], and [6,7] Ring Systems Using Baylis–Hillman Acetates
Author(s) -
Basavaiah Deevi,
Aravindu Kunche,
Kumar Katta Santosh,
Reddy Kanumuri Ramesh
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200901483
Subject(s) - chemistry , ring (chemistry) , intramolecular force , alkylation , michael reaction , friedel–crafts reaction , simple (philosophy) , organic chemistry , combinatorial chemistry , polymer chemistry , catalysis , philosophy , epistemology
A simple, convenient, and one‐pot synthesis of angularly fused [6‐7‐5], [6‐7‐6], [6‐7‐7], and [6,7] carbocyclic ring systems from Baylis–Hillman acetates through a strategy involving alkylation, formation of a vinyl chloride, and intramolecular cyclization (Friedel–Crafts or Michael reaction) is described.