p ‐(Benzyloxy)calix[8]arene Synthesis Revisited:  p ‐(Benzyloxy)calix[4]‐,  p ‐(Benzyloxy)calix[5]‐,  p ‐(Benzyloxy)calix[7]‐, and  p ‐(Benzyloxy)bis(homooxa)calix[4]arenes | Zendy

Huc Vincent | Zendy; Npetgat Eloïne | Zendy; Guérineau Vincent | Zendy; Bourcier Sophie | Zendy; Dos Santos Amandine | Zendy; Guillot Régis | Zendy; Baltaze JeanPierre | Zendy; Martini Cyril | Zendy

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p ‐(Benzyloxy)calix[8]arene Synthesis Revisited: p ‐(Benzyloxy)calix[4]‐, p ‐(Benzyloxy)calix[5]‐, p ‐(Benzyloxy)calix[7]‐, and p ‐(Benzyloxy)bis(homooxa)calix[4]arenes

Author(s) -

Huc Vincent,

Npetgat Eloïne,

Guérineau Vincent,

Bourcier Sophie,

Dos Santos Amandine,

Guillot Régis,

Baltaze JeanPierre,

Martini Cyril

Publication year - 2010

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200901405

Subject(s) - calixarene , chemistry , supramolecular chemistry , stereochemistry , phenol , combinatorial chemistry , organic chemistry , molecule

A detailed investigation of the 4‐(benzyloxy)phenol/formaldehyde reaction shows that along with the previously described p ‐(benzyloxy)calix[8]arene and p ‐(benzyloxy)calix[6]arene, others calixarenes are observed and easily recovered on a preparative scale. All these new calixarenes are opening interesting perspectives for the synthesis of new supramolecular hosts, easily functionalized at the para position under very mild conditions and/or exhibiting a deep hydrophobic pocket.

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