Palladium‐Catalyzed Alkenylation of 1,2,3‐Trizoles with Terminal Conjugated Alkenes by Direct C–H Bond Functionalization | Zendy

Jiang Huanfeng | Zendy; Feng Zhenning | Zendy; Wang Azhong | Zendy; Liu Xiaohang | Zendy; Chen Zhengwang | Zendy

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Palladium‐Catalyzed Alkenylation of 1,2,3‐Trizoles with Terminal Conjugated Alkenes by Direct C–H Bond Functionalization

Author(s) -

Jiang Huanfeng,

Feng Zhenning,

Wang Azhong,

Liu Xiaohang,

Chen Zhengwang

Publication year - 2010

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200901282

Subject(s) - chemistry , surface modification , palladium , conjugated system , catalysis , yield (engineering) , terminal (telecommunication) , oxidative coupling of methane , combinatorial chemistry , organic chemistry , polymer chemistry , polymer , telecommunications , materials science , computer science , metallurgy

A palladium‐catalyzed alkenylation of 1,2,3‐triazoles with terminal conjugated alkenes by direct C–H functionalization has been developed in the presence of Cu(OAc) 2 and dioxygen. A variety of terminal alkenes such as acrylates and styrenes can perform the direct oxidative coupling reactions with 1,2,3‐triazoles to afford the corresponding alkenylated products in 30–90 % yield.

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