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1,1′‐Diaryl‐Substituted Ferrocenes: Up to Three Hinges in Oligophenyleneethynylene‐Type Molecular Wires
Author(s) -
Baumgardt Ingmar,
Butenschön Holger
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200901252
Subject(s) - ferrocene , chemistry , hinge , thiophene , context (archaeology) , phenylene , molecular wire , stereochemistry , flexibility (engineering) , crystallography , molecule , combinatorial chemistry , organic chemistry , electrochemistry , polymer , electrode , physics , paleontology , statistics , mathematics , biology , classical mechanics
Molecular wires of the oligophenyleneethynylene (OPE)‐type are potentially rigid entities. The idea of the work reported herein was to replace some, not all, of the phenylene moieties with ferrocene units, thereby introducing limited conformational flexibility with the ferrocene units acting as hinges as a consequence of the facile rotation around the Cp–Fe–Cp axis. In this context, the syntheses of a number of 1,1′‐diaryl‐disubstituted ferrocene building blocks are described. The new terminal diynes 22 and 24 were used to construct the first representatives of ferrocene‐based molecular wires with three ferrocene hinges. The study includes an X‐ray structure analysis of the thiophene‐based diyne 24 as well as cyclovoltammetric analyses of a number of the compounds prepared.