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Stereodefined Access to 3‐Deoxy Sugars Through a Tandem Baylis–Hillman and Lewis Acid Catalyzed Reaction Sequence
Author(s) -
Radha Krishna Palakodety,
Manjuvani Applashetti,
Narsingam Mogili,
Raju Galla
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200901109
Subject(s) - chemistry , adduct , lewis acids and bases , tandem , baylis–hillman reaction , catalysis , sequence (biology) , stereochemistry , sugar , organic chemistry , combinatorial chemistry , biochemistry , materials science , composite material
An innovative synthetic protocol is reported for the ready access to 3‐deoxy sugars in both D and L forms as exclusive products (des >95 %) in high yields through a stereodefined Lewis acid catalyzed reaction sequence of the sugar‐derived Baylis–Hillman adducts.