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Total Synthesis of a Diarylheptanoid, Rhoiptelol B
Author(s) -
Reddy Chada Raji,
Rao Nagavaram Narsimha,
Srikanth Boinapally
Publication year - 2010
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200901041
Subject(s) - chemistry , aldol reaction , total synthesis , stereoselectivity , stereochemistry , organic chemistry , catalysis
A stereoselective total synthesis of rhoiptelol B has been accomplished for the first time. The four asymmetric centers were efficiently generated through Keck allylation, Jacobson epoxidation Aldol reaction and reductive etherification as the key steps.