Highly Efficient Fluorine‐Promoted Intramolecular Condensation of Benzo[ c ]phenanthrene: A New Prospective on Direct Fullerene Synthesis | Zendy

Amsharov Konstantin Yu. | Zendy; Kabdulov Mikhail A. | Zendy; Jansen Martin | Zendy

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Highly Efficient Fluorine‐Promoted Intramolecular Condensation of Benzo[ c ]phenanthrene: A New Prospective on Direct Fullerene Synthesis

Author(s) -

Amsharov Konstantin Yu.,

Kabdulov Mikhail A.,

Jansen Martin

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900976

Subject(s) - chemistry , phenanthrenes , intramolecular force , fluorine , phenanthrene , fullerene , condensation , selectivity , surface modification , condensation reaction , flash vacuum pyrolysis , organic chemistry , photochemistry , combinatorial chemistry , pyrolysis , catalysis , physics , thermodynamics

Various functional groups have been tested as alternative promoters of the intramolecular condensation of benzo[ c ]phenanthrene under flash vacuum pyrolysis conditions. Methyl and fluorine functionalization were found to be promising approaches. Unexpectedly high selectivity was observed in the cyclization of fluorinated benzo[ c ]phenanthrenes. The mechanism for the condensation reaction and the advantages of fluorine as a promoter for the rational synthesis of fullerenes are discussed.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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