Merging of E2 and E1cb Reaction Mechanisms: A Combined Theoretical and Experimental Study | Zendy

Mosconi Edoardo | Zendy; De Angelis Filippo | Zendy; Belpassi Leonardo | Zendy; Tarantelli Francesco | Zendy; Alunni Sergio | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Merging of E2 and E1cb Reaction Mechanisms: A Combined Theoretical and Experimental Study

Author(s) -

Mosconi Edoardo,

De Angelis Filippo,

Belpassi Leonardo,

Tarantelli Francesco,

Alunni Sergio

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900906

Subject(s) - chemistry , reactivity (psychology) , computational chemistry , kinetic energy , elimination reaction , combinatorial chemistry , nanotechnology , organic chemistry , quantum mechanics , physics , medicine , alternative medicine , materials science , pathology

By combining the results of kinetic measurements with DFT calculations we provide a clear‐cut evidence of the merging between the E2 and E1cb reaction mechanisms for a large series of leaving groups. Our results solve a long‐debated issue in chemical reactivity with profound implications both from a fundamental and biological point of view, thus paving the way to further investigations with different substrates.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research