Diversity‐Oriented Synthesis of Chlorinated Arenes by One‐Pot Cyclizations of 4‐Chloro‐1,3‐bis(trimethylsilyloxy)buta‐1,3‐dienes | Zendy

Wolf Verena | Zendy; Adeel Muhammad | Zendy; Reim Stefanie | Zendy; Villinger Alexander | Zendy; Fischer Christine | Zendy; Langer Peter | Zendy

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Diversity‐Oriented Synthesis of Chlorinated Arenes by One‐Pot Cyclizations of 4‐Chloro‐1,3‐bis(trimethylsilyloxy)buta‐1,3‐dienes

Author(s) -

Wolf Verena,

Adeel Muhammad,

Reim Stefanie,

Villinger Alexander,

Fischer Christine,

Langer Peter

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900816

Subject(s) - chemistry , aryl , stereochemistry , medicinal chemistry , organic chemistry , alkyl

A variety of 3‐chlorosalicylates were prepared by one‐potcyclizations of the first reported 4‐chloro‐1,3‐bis(trimethylsilyloxy)buta‐1,3‐dienes with various 1,3‐dielectrophiles. These include cyclizations with 3‐silyloxy‐2‐en‐1‐ones, 3‐aryl‐3‐silyloxy‐2‐en‐1‐ones, 1‐methoxy‐1‐en‐3‐ones, 1,1‐bis(methylthio)‐1‐en‐3‐ones, 3‐oxo orthoesters, 1,1,3,3‐tetraethoxypropanes, 1,1‐diacetylcyclopropane, and 3‐formylchromones. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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