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An Efficient (2‐Aminoarenethiolato)copper(I) Complex for the Copper‐Catalysed Huisgen Reaction (CuAAC)
Author(s) -
Fabbrizzi Pierangelo,
Cicchi Stefano,
Brandi Alberto,
Sperotto Elena,
van Koten Gerard
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900779
Subject(s) - chemistry , copper , catalysis , click chemistry , combinatorial chemistry , solvent , polymer chemistry , organic chemistry
Abstract A (2‐aminoarenethiolato)copper(I) complex has been used as an efficient catalyst (1 mol‐%) for the copper‐catalysedHuisgen reaction (CuAAC) of azides and terminal alkynes in an organic solvent. The reaction was also extremely effective in CH 2 Cl 2 allowing the complete decoration of dendrimeric scaffolds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)