Ligand‐Free Iron/Copper‐Cocatalyzed Amination of Aryl Iodides | Zendy

Wu XiaoFeng | Zendy; Darcel Christophe | Zendy

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Ligand‐Free Iron/Copper‐Cocatalyzed Amination of Aryl Iodides

Author(s) -

Wu XiaoFeng,

Darcel Christophe

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900588

Subject(s) - chemistry , amination , aryl , iodide , ammonia , ligand (biochemistry) , aqueous solution , ethanol , copper , combinatorial chemistry , organic chemistry , catalysis , biochemistry , alkyl , receptor

The Fe 2 O 3 /CuI system efficiently catalyzes the direct amination of aryl iodides with aqueous ammonia in ethanol at 90 °C under aerobic conditions. No ligand was used to perform such reaction. A very wide variety of functional groups was tolerated on the aryl iodide partner. This procedure is economically and environmentally attractive as a result of the use of aqueous ammonia and ethanol.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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