A Novel Approach to the Practical Synthesis of Sulfides: An InBr 3 –Et 3 SiH Catalytic System Promoted the Direct Reductive Sulfidation of Acetals with Disulfides | Zendy

Sakai Norio | Zendy; Moritaka Kohei | Zendy; Konakahara Takeo | Zendy

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A Novel Approach to the Practical Synthesis of Sulfides: An InBr 3 –Et 3 SiH Catalytic System Promoted the Direct Reductive Sulfidation of Acetals with Disulfides

Author(s) -

Sakai Norio,

Moritaka Kohei,

Konakahara Takeo

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900566

Subject(s) - chemistry , sulfidation , sulfide , catalysis , acetal , conjugated system , organic chemistry , polymer

We have demonstrated a facile and direct synthesis of sulfide derivatives using acetals and ketals, derived from aromatic/conjugated aldehydes and aromatic ketones, with disulfides and the InBr 3 –Et 3 SiH reducing system. We also succeeded in developing an unprecedented one‐pot preparation of an aliphatic sulfide from a disulfide and an aliphatic acetal. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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