Versatile Synthesis of Secondary 2‐Amino Thiols and/or Their Disulfides via Thiazolinium Salts | Zendy

Mercey Guillaume | Zendy; Lohier JeanFrançois | Zendy; Gaumont AnnieClaude | Zendy; Levillain Jocelyne | Zendy; Gulea Mihaela | Zendy

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Versatile Synthesis of Secondary 2‐Amino Thiols and/or Their Disulfides via Thiazolinium Salts

Author(s) -

Mercey Guillaume,

Lohier JeanFrançois,

Gaumont AnnieClaude,

Levillain Jocelyne,

Gulea Mihaela

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900514

Subject(s) - chemistry , salt (chemistry) , sulfur , thiol , combinatorial chemistry , organic chemistry , amino acid , biochemistry

Commercially available β‐amino alcohols have been transformed into various secondary β‐amino thiols and/or their disulfides by using methyl dithioacetate as a source of sulfur. The transformation involves a thiazolinium salt as a versatile key intermediate, which enables easy modulation of the product structure by varying the substituents on the heterocycle and the N ‐alkylating agent.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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