N ‐Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles | Zendy

Mizota Isao | Zendy; Matsuda Yuri | Zendy; Hachiya Iwao | Zendy; Shimizu Makoto | Zendy

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N ‐Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

Author(s) -

Mizota Isao,

Matsuda Yuri,

Hachiya Iwao,

Shimizu Makoto

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900457

Subject(s) - acrolein , chemistry , nucleophile , isomerization , dehydration , nucleophilic addition , organic chemistry , combinatorial chemistry , medicinal chemistry , catalysis , biochemistry

Two practical methods have been developed for the preparation of N ‐allylideneamines 1b , c . One involves the isomerization of propargylamines and the other the dehydration of acrolein. N ‐Allylideneamines 1b , c thus prepared were used as efficient substrates for 1,4‐ and 1,2‐double nucleophilic addition reactions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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