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Generation of Prenylhafnium and α‐Selective Addition to Imines
Author(s) -
Shibata Ikuya,
Miyamoto Shinji,
Tsunoi Shinji,
Sakamoto Kazuya,
Baba Akio
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900445
Subject(s) - transmetalation , chemistry , addition reaction , combinatorial chemistry , organic chemistry , catalysis
Allylhafnium compounds were generated by transmetalation between allyl‐SnBu 3 and HfCl 4 in EtCN. A highly α‐selective addition reaction of prenyltributyltin to imines was observed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)