Premium
Facile Synthesis of Hyper‐Branched Tetraphosphanes and Tetraphosphane Chalcogenides
Author(s) -
Trofimov Boris A.,
Malysheva Svetlana F.,
Belogorlova Nataliya A.,
Kuimov Vladimir A.,
Albanov Alexander I.,
Gusarova Nina K.
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900382
Subject(s) - chemistry , pentaerythritol , yield (engineering) , ether , organic chemistry , polymer chemistry , medicinal chemistry , materials science , fire retardant , metallurgy
Novel families of hyper‐branched tertiary tetraphosphanes, tetraphosphane sulfides, and tetraphosphane selenides were synthesized in 72–97 % yield by treating secondary phosphanes, phosphane sulfides, and phosphane selenides with the tetravinyl ether of pentaerythritol (UV irradiation, room temp. or AIBN, 65 °C). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)