Facile Synthesis of Hyper‐Branched Tetraphosphanes and Tetraphosphane Chalcogenides | Zendy

Trofimov Boris A. | Zendy; Malysheva Svetlana F. | Zendy; Belogorlova Nataliya A. | Zendy; Kuimov Vladimir A. | Zendy; Albanov Alexander I. | Zendy; Gusarova Nina K. | Zendy

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Facile Synthesis of Hyper‐Branched Tetraphosphanes and Tetraphosphane Chalcogenides

Author(s) -

Trofimov Boris A.,

Malysheva Svetlana F.,

Belogorlova Nataliya A.,

Kuimov Vladimir A.,

Albanov Alexander I.,

Gusarova Nina K.

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900382

Subject(s) - chemistry , pentaerythritol , yield (engineering) , ether , organic chemistry , polymer chemistry , medicinal chemistry , materials science , fire retardant , metallurgy

Novel families of hyper‐branched tertiary tetraphosphanes, tetraphosphane sulfides, and tetraphosphane selenides were synthesized in 72–97 % yield by treating secondary phosphanes, phosphane sulfides, and phosphane selenides with the tetravinyl ether of pentaerythritol (UV irradiation, room temp. or AIBN, 65 °C). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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