Combinations of Alkyllithiums and Lithium Aminoalkoxides for Generation of Functional Pyridine Organometallics and Derivatives | Zendy

Gros Philippe C. | Zendy; Fort Yves | Zendy

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Combinations of Alkyllithiums and Lithium Aminoalkoxides for Generation of Functional Pyridine Organometallics and Derivatives

Author(s) -

Gros Philippe C.,

Fort Yves

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900324

Subject(s) - chemistry , superbase , reagent , lithium (medication) , metalation , pyridine , combinatorial chemistry , carbanion , organic chemistry , catalysis , medicine , endocrinology

This account covers the current status of pyridine metallation with alkyllithium/lithium aminoalkoxide reagents and follows a previous review focusing on pioneering works on the n BuLi/LiDMAE reagent. An updated overview of the scope of metallation with this superbase is presented, together with the development of new reagents and synthetic applications based on selective lithiation methodology.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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