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New Electrochemically Generated Polymeric Pd Complexes as Heterogeneous Catalysts for Suzuki Cross‐Coupling Reactions
Author(s) -
Bandini Marco,
Pietrangelo Agostino,
Sinisi Riccardo,
UmaniRonchi Achille,
Wolf Michael O.
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900306
Subject(s) - chemistry , palladium , catalysis , suzuki reaction , coupling reaction , polymer chemistry , graphite , heterogeneous catalysis , polymerization , combinatorial chemistry , chemical engineering , organic chemistry , polymer , engineering
Electrochemically generated films of polymerized (diamino‐oligothiophene)palladium complexes as heterogeneous catalysts for Suzuki cross‐coupling reactions are reported. The electrodeposition of these polymeric species onto porous graphite electrodes allows for easy removal of the organometallic species from the reaction mixture and convenient reuse in subsequent (up to 6) reactions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)