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An Easy and Multigram‐Scale Synthesis of Versatile AA‐ and AB‐Type m ‐Terphenylenes as Building Blocks for Kinked Polyphenylenes
Author(s) -
Kissel Patrick,
Breitler Simon,
Reinmüller Viktoria,
Lanz Patrick,
Federer Lukas,
Schlüter A. Dieter,
Sakamoto Junji
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900263
Subject(s) - chemistry , halide , combinatorial chemistry , scale (ratio) , masking (illustration) , type (biology) , coupling (piping) , stereochemistry , organic chemistry , composite material , art , ecology , physics , quantum mechanics , visual arts , biology , materials science
A set of m ‐terphenylenes having a readily functionalizable hydroxy group as well as either symmetric AA‐type or unsymmetric AB‐type halide termini have been prepared on a several‐gram scale. The synthesis was carried out on the basis of the Suzuki–Miyaura cross‐coupling in combination with a TMS masking strategy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)