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New Efficient Route to Fused Aryltetrahydroindolizinones via N ‐Acyliminium Intermediates
Author(s) -
Chiurato Matteo,
Routier Sylvain,
Troin Yves,
Guillaumet Gérald
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200900195
Subject(s) - iminium , chemistry , combinatorial chemistry , ion , mechanism (biology) , stereochemistry , organic chemistry , philosophy , epistemology
Straightforward routes to fused tetrahydroindolizinones by two routes A and B , starting either from 2‐formylbenzoic acid and esters or from β‐hydroxy lactones via acyl iminium ions, are described. A plausible mechanism and limitations are given. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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