Various Synthetic Routes to a Gable‐Like Bis(porphyrin) Constructed on a 1,10‐Phenanthroline Chelate | Zendy

Beyler Maryline | Zendy; Beemelmanns Christine | Zendy; Heitz Valérie | Zendy; Sauvage JeanPierre | Zendy

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Various Synthetic Routes to a Gable‐Like Bis(porphyrin) Constructed on a 1,10‐Phenanthroline Chelate

Author(s) -

Beyler Maryline,

Beemelmanns Christine,

Heitz Valérie,

Sauvage JeanPierre

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200900149

Subject(s) - porphyrin , phenanthroline , chemistry , gable , derivative (finance) , chelation , covalent bond , polymer chemistry , combinatorial chemistry , organic chemistry , structural engineering , roof , financial economics , engineering , economics

Three different synthetic routes to obtain a gable‐like bis(porphyrin) are described. The two porphyrins are covalently linked to a 2,9‐diphenyl‐1,10‐phenanthroline chelate. One way to gain access to the bis(porphyrin) relies on the simultaneous construction of two porphyrins on a 2,9‐bis( para ‐formylphenyl)‐1,10‐phenanthroline, whereas the other two are based on Suzuki cross‐coupling reactions between a presynthesised porphyrin and an appropriate phenanthroline derivative.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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