Carbonylative Suzuki–Miyaura Coupling of Arylboronic Acids with Aryl Iodides Catalyzed by the MCM‐41‐Supported Bidentate Phosphane Palladium(II) Complex | Zendy

Cai Mingzhong | Zendy; Zheng Guomin | Zendy; Zha Lingfang | Zendy; Peng Jian | Zendy

Premium

Carbonylative Suzuki–Miyaura Coupling of Arylboronic Acids with Aryl Iodides Catalyzed by the MCM‐41‐Supported Bidentate Phosphane Palladium(II) Complex

Author(s) -

Cai Mingzhong,

Zheng Guomin,

Zha Lingfang,

Peng Jian

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200801253

Subject(s) - chemistry , palladium , anisole , aryl , denticity , catalysis , carbon monoxide , selectivity , organic chemistry , medicinal chemistry , carbonylation , polymer chemistry , crystal structure , alkyl

The first heterogeneous carbonylative Suzuki–Miyaura cross‐coupling reaction of arylboronic acids with aryl iodides under an atmospheric pressure of carbon monoxide has been achieved in anisole at 80 °C in the presence of a catalytic amount of an MCM‐41‐supported bidentate phosphane palladium(II) complex (MCM‐41‐2P‐Pd II ), yielding unsymmetrical biaryl ketones in good‐to‐high yields. This polymeric palladium catalyst exhibited higher activity and selectivity than [PdCl 2 (PPh 3 ) 2 ] and can be reused at least 10 times without any decrease in activity. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research