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Novel Photochemical Reactions of Phosphonium‐Iodonium Ylides: Synthesis of Phosphonium‐Substituted Oxazoles
Author(s) -
Matveeva Elena D.,
Podrugina Tatyana A.,
Pavlova Anna S.,
Mironov Andrey V.,
Gleiter Rolf,
Zefirov Nikolai S.
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200801251
Subject(s) - chemistry , phosphonium , oxazole , propionitrile , benzonitrile , acetonitrile , chemoselectivity , nitrile , photochemistry , organic chemistry , medicinal chemistry , catalysis
Irradiation of the mixed phosphonium‐iodonium ylides 4 – 6 in the presence of acetonitrile, propionitrile, and benzonitrile yielded the oxazole derivatives 9a – 9c , 10a – 10c , and 11a – 11c in 30 %–50 % yields. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)