Cycloaddition Reactions of 1‐Alkyl‐3,4,5‐triphenyl‐1,2‐diphosphacyclopenta‐2,4‐dienes | Zendy

Miluykov Vasili | Zendy; Bezkishko Ilya | Zendy; Zagidullin Almaz | Zendy; Sinyashin Oleg | Zendy; Lönnecke Peter | Zendy; HeyHawkins Evamarie | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Cycloaddition Reactions of 1‐Alkyl‐3,4,5‐triphenyl‐1,2‐diphosphacyclopenta‐2,4‐dienes

Author(s) -

Miluykov Vasili,

Bezkishko Ilya,

Zagidullin Almaz,

Sinyashin Oleg,

Lönnecke Peter,

HeyHawkins Evamarie

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200801181

Subject(s) - chemistry , cycloaddition , alkyl , maleic anhydride , reactivity (psychology) , alkylation , medicinal chemistry , thermal decomposition , maleimide , organic chemistry , sodium azide , catalysis , copolymer , medicine , alternative medicine , pathology , polymer

1‐Alkyl‐3,4,5‐triphenyl‐1,2‐diphosphacyclopenta‐2,4‐dienes 1 , obtained by alkylation of sodium 1,2‐diphospha‐3,4,5‐triphenylcyclopentadienide, exhibit dual reactivity in cycloaddition reactions: as dienes (with maleic anhydride and maleimide) or as dienophiles (with 2,3‐dimethylbutadiene). Thermolysis of 1 occurs with a [1,5] sigmatropic shift to form a [2+2] cyclodimerization product.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research