On the Stereoselectivity of Alkenoxyl Radical 6‐ exo ‐ trig  Cyclizations | Zendy

Schneiders Nina | Zendy; Gottwald Thomas | Zendy; Hartung Jens | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

On the Stereoselectivity of Alkenoxyl Radical 6‐ exo ‐ trig Cyclizations

Author(s) -

Schneiders Nina,

Gottwald Thomas,

Hartung Jens

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200801116

Subject(s) - chemistry , stereoselectivity , tetrahydropyran , radical , ring (chemistry) , stereochemistry , closure (psychology) , radical cyclization , organic chemistry , catalysis , economics , market economy

The investigated set of 6‐ exo ‐ trig cyclizations occurs irreversibly and justifies the use of tetrahydropyran‐derived transition structures for rationalizing 2,6‐ cis , 2,5‐ trans , and 2,4‐ cis stereoselectivity in ring‐closure reactions of 1‐, 2‐, and 3‐phenyl‐6‐methyl‐5‐hepten‐1‐oxyl radicals. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research