An Efficient Molybdenum(VI)‐Catalyzed Direct Substitution of Allylic Alcohols with Nitrogen, Oxygen, and Carbon Nucleophiles | Zendy

Yang Hongwei | Zendy; Fang Ling | Zendy; Zhang Ming | Zendy; Zhu Chengjian | Zendy

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An Efficient Molybdenum(VI)‐Catalyzed Direct Substitution of Allylic Alcohols with Nitrogen, Oxygen, and Carbon Nucleophiles

Author(s) -

Yang Hongwei,

Fang Ling,

Zhang Ming,

Zhu Chengjian

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800976

Subject(s) - chemistry , allylic rearrangement , nucleophile , catalysis , molybdenum , oxygen , carbon fibers , nucleophilic substitution , nitrogen , substitution reaction , medicinal chemistry , organic chemistry , materials science , composite number , composite material

Direct nucleophilic substitution of allylic alcohols with various nitrogen, oxygen, and carbon nucleophiles catalyzed by MoO 2 (acac) 2 was realized. The corresponding products were obtained in moderate‐to‐excellent yields. Studies of the reaction mechanism showed that a carbenium intermediate was formed in the transition state. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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