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An Efficient Molybdenum(VI)‐Catalyzed Direct Substitution of Allylic Alcohols with Nitrogen, Oxygen, and Carbon Nucleophiles
Author(s) -
Yang Hongwei,
Fang Ling,
Zhang Ming,
Zhu Chengjian
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200800976
Subject(s) - chemistry , allylic rearrangement , nucleophile , catalysis , molybdenum , oxygen , carbon fibers , nucleophilic substitution , nitrogen , substitution reaction , medicinal chemistry , organic chemistry , materials science , composite number , composite material
Direct nucleophilic substitution of allylic alcohols with various nitrogen, oxygen, and carbon nucleophiles catalyzed by MoO 2 (acac) 2 was realized. The corresponding products were obtained in moderate‐to‐excellent yields. Studies of the reaction mechanism showed that a carbenium intermediate was formed in the transition state. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)