Synthesis and Use of Achiral Oxazolidine‐2‐thiones in Selective Preparation of  trans  2,5‐Disubstituted Tetrahydrofurans | Zendy

Jalce Gaël | Zendy; Franck Xavier | Zendy; Figadère Bruno | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis and Use of Achiral Oxazolidine‐2‐thiones in Selective Preparation of trans 2,5‐Disubstituted Tetrahydrofurans

Author(s) -

Jalce Gaël,

Franck Xavier,

Figadère Bruno

Publication year - 2009

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800907

Subject(s) - chemistry , lactol , oxazolidine , steric effects , glycosylation , stereochemistry , organic chemistry , lactone , biochemistry

The use of achiral N ‐acetyloxazolidine‐2‐thiones in the C ‐glycosylation of lactol acetates has allowed us to prepare with high diastereoselectivity the expected trans 2,5‐disubstituted tetrahydrofurans. A study based on the role of the steric hindrance of the N ‐acetyloxazolidine‐2‐thiones is reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research