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Synthesis of Chlamydocin by Chelate‐Claisen Rearrangement
Author(s) -
Quirin Christian,
Kazmaier Uli
Publication year - 2009
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200800890
Subject(s) - chemistry , claisen rearrangement , chelation , allylic rearrangement , stereochemistry , carroll rearrangement , organic chemistry , catalysis
Chelate‐Claisen rearrangement of a chiral allylic ester allows the synthesis of the unusual epoxyketo amino acid Aoe found in chlamydocin, one representative of a group of peptide‐based HDAc inhibitors. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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