Salt‐Free Synthesis of Tertiary Amines by Ruthenium‐Catalyzed Amination of Alcohols | Zendy

Tillack Annegret | Zendy; Hollmann Dirk | Zendy; Mevius Kathleen | Zendy; Michalik Dirk | Zendy; Bähn Sebastian | Zendy; Beller Matthias | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Salt‐Free Synthesis of Tertiary Amines by Ruthenium‐Catalyzed Amination of Alcohols

Author(s) -

Tillack Annegret,

Hollmann Dirk,

Mevius Kathleen,

Michalik Dirk,

Bähn Sebastian,

Beller Matthias

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800671

Subject(s) - chemistry , amination , ruthenium , catalysis , yield (engineering) , alkylation , organic chemistry , reductive amination , cyclic amines , salt (chemistry) , pyrrole , materials science , metallurgy

The amination of secondary alcohols to give tertiary amines in the presence of different in situ generated ruthenium catalysts has been investigated in detail. By applying a combination of [Ru 3 (CO) 12 ] and N ‐phenyl‐2‐(dicyclohexylphosphanyl)pyrrole as the catalyst, cyclic amines can be alkylated with different alcohols in high yield, whereas aliphatic amines gave transalkylation side products.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research