Synthesis of the L‐Acid (C1–C18) Fragment of Pamamycin‐593 and De‐ N ‐methylpamamycin‐579 | Zendy

Miura Ayako | Zendy; Takigawa Shinya | Zendy; Furuya Yukito | Zendy; Yokoo Yusuke | Zendy; Kuwahara Shigefumi | Zendy; Kiyota Hiromasa | Zendy

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Synthesis of the L‐Acid (C1–C18) Fragment of Pamamycin‐593 and De‐ N ‐methylpamamycin‐579

Author(s) -

Miura Ayako,

Takigawa Shinya,

Furuya Yukito,

Yokoo Yusuke,

Kuwahara Shigefumi,

Kiyota Hiromasa

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800600

Subject(s) - chemistry , acetylide , fragment (logic) , stereochemistry , aldehyde , nucleophile , nucleophilic addition , organic chemistry , catalysis , computer science , programming language

The L‐acid (C1–C18) fragment of pamamycin‐593 and de‐ N ‐methylpamamycin‐579, strong aerial mycelium‐inducers of Streptomyces alboniger , was synthesized using a cis ‐selective iodoetherification and a nucleophilic addition of a cerium acetylide to an aldehyde as the key steps. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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