Taxpropellane: A Novel Taxane with an Unprecedented Polycyclic Skeleton from the Needles of  Taxus canadensis | Zendy

Zhang ManLi | Zendy; Dong Mei | Zendy; Huo ChangHong | Zendy; Li LiGeng | Zendy; Sauriol Françoise | Zendy; Shi QingWen | Zendy; Gu YuCheng | Zendy; Makabe Hidefumi | Zendy; Kiyota Hiromasa | Zendy

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Taxpropellane: A Novel Taxane with an Unprecedented Polycyclic Skeleton from the Needles of Taxus canadensis

Author(s) -

Zhang ManLi,

Dong Mei,

Huo ChangHong,

Li LiGeng,

Sauriol Françoise,

Shi QingWen,

Gu YuCheng,

Makabe Hidefumi,

Kiyota Hiromasa

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800587

Subject(s) - taxane , chemistry , propellane , stereochemistry , ring (chemistry) , cycloaddition , skeleton (computer programming) , diterpene , organic chemistry , bicyclic molecule , catalysis , medicine , cancer , breast cancer , computer science , programming language

Taxpropellane, the first example of a taxane with an unprecedented 6/5/5/6/4/5‐membered ring hexacyclic skeleton ([3.3.2]propellane), was isolated from the needles of Taxus canadensis . This compound would be derived from a normal 6/8/6 taxane by a [2+2] cycloaddition reaction between the 3,4‐ and 11,12‐double bonds. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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