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Stereoselective Synthesis of the Naturally Occurring 2‐Pyranone Dodoneine
Author(s) -
ÁlvarezBercedo Paula,
Falomir Eva,
Murga Juan,
Carda Miguel,
Marco J. Alberto
Publication year - 2008
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200800389
Subject(s) - stereocenter , chemistry , stereoselectivity , ring closing metathesis , metathesis , ring (chemistry) , stereochemistry , salt metathesis reaction , enantioselective synthesis , organic chemistry , catalysis , polymer , polymerization
The first total synthesis of the naturally occurring dihydropyranone dodoneine is reported. Asymmetric allylation reactions were used for the stereoselective generation of the two stereogenic centers. The pyranone ring was created by ring‐closing metathesis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)