Synthesis of Oligophenylenevinylene Heptamers Substituted with Fullerene Moieties | Zendy

Gégout Aline | Zendy; Holler Michel | Zendy; FigueiraDuarte Teresa M. | Zendy; Nierengarten JeanFrançois | Zendy

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Synthesis of Oligophenylenevinylene Heptamers Substituted with Fullerene Moieties

Author(s) -

Gégout Aline,

Holler Michel,

FigueiraDuarte Teresa M.,

Nierengarten JeanFrançois

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800312

Subject(s) - chemistry , fullerene , cyclic voltammetry , electrochemistry , derivative (finance) , combinatorial chemistry , carboxylic acid , alcohol , organic chemistry , electrode , financial economics , economics

Oligophenylenevinylene (OPV) derivatives substituted with one or two fullerene subunits have been prepared starting from a fullerene carboxylic acid derivative and OPV heptamers bearing one or two alcohol functions. The electrochemical properties of the resulting C 60 ‐OPV derivatives have been investigated by cyclic voltammetry. Whereas the fist reduction of both C 60 –OPV conjugates is centered on the C 60 unit, the oxidation is centered on the OPV rod. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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