First Synthesis of Bi‐ and Tricyclic α,β‐Unsaturated δ‐Oxacaprolactams from Cyclic Imines via Ring‐Closing Metathesis | Zendy

Watzke Martin | Zendy; Schulz Knut | Zendy; Johannes Katharina | Zendy; Ullrich Pasqual | Zendy; Martens Jürgen | Zendy

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First Synthesis of Bi‐ and Tricyclic α,β‐Unsaturated δ‐Oxacaprolactams from Cyclic Imines via Ring‐Closing Metathesis

Author(s) -

Watzke Martin,

Schulz Knut,

Johannes Katharina,

Ullrich Pasqual,

Martens Jürgen

Publication year - 2008

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.200800254

Subject(s) - ring closing metathesis , chemistry , metathesis , ruthenium , salt metathesis reaction , closing (real estate) , tricyclic , ring (chemistry) , catalysis , organic chemistry , combinatorial chemistry , political science , law , polymerization , polymer

A new class of α,β‐unsaturated δ‐oxacaprolactams was synthesized from imines as starting material. The synthetic procedure is based on an acyl chloride addition in the first step, followed by a ring‐closing metathesis using a ruthenium catalyst. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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