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Perfluoroalkylation through Cross‐Metathesis between Alkenes and (Perfluoroalkyl)propenes
Author(s) -
Eignerová Barbara,
Dračínský Martin,
Kotora Martin
Publication year - 2008
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.200800230
Subject(s) - chemistry , metathesis , organic chemistry , catalysis , selectivity , salt metathesis reaction , combinatorial chemistry , polymerization , polymer
A new approach to perfluoroalkylated compounds based on cross‐metathesis between perfluoropropenes and terminal alkenes has been developed. The reaction is catalysed with high efficiency and selectivity by the Hoveyda–Grubbs second‐generation catalyst under mild reaction conditions. The method is applicable to a wide range of compounds, such as vinylaromatics, isoprenoids and saccharides.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)